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Historical Review of the Evolution of
Detergents:
The symbol used by the ancient Egyptians to
represent a launder was a pair of legs immersed
in water. This choice was logical, because at
this time the standard way to launder clothes
was to tread on them. But simple laundry was
subjected to purely mechanical treatment.
It has long been known, however, that the
washing power can be increased in various ways:
Rain water, for example, was found to be more
suitable for washing than well water.
Hot water also was found to have more washing
power than cold water.
The Egyptians even used soda as a wash additive;
this was later supplemented with nasilicate.
Soap is the oldest surfactant; it was known to
the Sumerians as early as 2500 BC.
Soap was regarded as a remedy and a cosmetic
especially in hair pomade.
Only in the last 1000 years has it come to be
used as a general purpose washing and laundering
agent.
Notorious for its sensitivity to water hardness,
water was gradually replaced by synthetic
surfactants with more favorable characteristics.
Following World War II other ingredients for
improving detergency performance were
introduced.
Chief among these are the following:
Complexion agents (STTP)
Ion exchanging (ZEOLITHE)
Soil anti-redepsition agents
EnzymesFluorescent whitening agents (FWA)
Foam regulators
Bleaching activators
Complex agents
Polymers
Table 1 shows the historical evolution of
surfactants with the concurrent development in
washing machines:
History dates about washing
Year |
|
Washing Equipment |
2500 A.C |
Soap cosmetics (Sumerians) |
By hands |
2000 A.C |
Soap (Egypt) |
By hands |
1000 P.C |
Soap (Cleaning agent) |
By hands |
1876 |
Soap- soda- Na silicate |
Boiler |
1907 |
Soap- soda- Na silicate- per borate |
Wooden Vat |
1913 |
Protease pancreatic enzymes |
Machine |
1920 |
|
Metal tube agitator |
1932 |
Synthetic surfactants (F.alchohol sulfate) |
Washing Machines |
1940 |
Anti-red position agents (C.M.C) |
Automatic agitator, Washing machine (USA) |
1950 |
Perfumes- foam regulators- optical brightener |
|
1954 |
Cationic- anionic- non ionic surfactants |
Semi automatic machine frontal door |
1957 |
|
Semi automatic drum machine, spinning separately (Europe) |
1962 |
|
Semi automatic drum machine, spinning separately (Europe) |
1963 |
Protease (microbe based enzymes) |
Fully automatic drum type washing machine |
1965 |
|
Wash dryer |
1970 |
STTP |
|
1972 |
Bleach activates (T A G U) |
|
1976 |
Zeolithe 4A- silicon oils |
|
1984 |
Polymers |
|
1988 |
Concentrated detergents |
|
1990 |
Phosphate free products |
|
1994/1999 |
Ultra compact- megaperls tablets |
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